The Solid State Questions and Answers Part-1

1. For two ionic solids CaO and KI, identify the wrong statement amongst the following :
a) The lattice energy of CaO is much large than that of KI
b) KI is more soluble in water
c) KI has higher melting point
d) CaO has higher melting point

Answer: c
Explanation: KI has higher melting point

2. For a covalent solid, the units which occupy lattice points are:
a) atoms
b) ions
c) molecules
d) electrons

Answer: a
Explanation: atoms

3. Graphite is a
a) molecular solid
b) covalent solid
c) ionic solid
d) metallic solid

Answer: b
Explanation: Graphite is a covalent solid

4. Which of the following is not a crystalline solid?
a) KCl
b) CsCl
c) Glass
d) Rhombic S

Answer: c
Explanation: Glass is amorphous solid

5. Among solids, the highest melting point is exhibited by
a) Covalent solids
b) Ionic solids
c) Pseudo solids
d) Molecular solids

Answer: a
Explanation: Covalent as in case of diamond

6. The major binding force of diamond, silicon and quartz is
a) electrostatic force
b) electrical attraction
c) covalent bond force
d)non-covalent bond force

Answer: c
Explanation: Covalent bond force

7. The maximum proportion of available volume that can be filled by hard spheres in diamond is
a) 0.52
b) 0.34
c) 0.32
d) 0.68

Answer: b
Explanation: The volume to be filled by hard spheres in diamond is 0.34.

8. The packing fraction for a body-centred cubic is
a) 0.42
b) 0.53
c) 0.68
d) 0.82

Answer: c
Explanation: The p.f. for body centred cube = 0.68

9.In a solid AB having the NaCl type structure, ‘A’ atoms occupy the corners of the cubic unit cell. If all the facecentred atoms along one of the axes are removed, then the resultant stoichiometry of the solid is
a) \[AB_{2}\]
b) \[A_{2}B\]
c) \[A_{4}B_{3}\]
d) \[A_{3}B_{4}\]

Answer: d
Explanation:
q9

10. A substance \[A_{x}B_{y}\]  crystallizes in a face centred cubic (fcc) lattice in which atoms ‘A’ occupy each corner of the cube and atoms ‘B’ occupy the centres of each face of the cube. Identify the correct composition of the substance \[A_{x}B_{y}\]
a) \[AB_{3}\]
b) \[A_{4}B_{3}\]
c) \[A_{3}B\]
d) Composition can’t be specified

Answer: a
Explanation:
q10